A paper co-authored by Professor Yuichi Kamiya of Hokkaido University’s Faculty of Environmental Earth Science has been published in Bulletin of Chemical Reaction Engineering & Catalysis.
- Nurdina, R. A., Kamiya, Y., Hatmanto, A. D., Pambudi, F. I., Suyanta, S., Nuryono, N. (2025). Ultrasonic-Assisted Transesterification of Tripalmitin Using Limestone-Derived CaO Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 20 (4), 672-682
DOI:10.9767/bcrec.20456
Abstract
In producing palm oil-based biodiesel (fatty acid methyl esters) through the transesterification of triglycerides with methanol, a high-performance and straightforward catalyst is required. This research studies the synthesis and characterization of limestone-derived calcium oxide as a heterogeneous base catalyst for the transesterification of tripalmitin, a representation of palm oil triglycerides, with methanol to produce methyl palmitate. Limestone was calcined at 800 °C to produce CaO. The resulting catalyst was characterized using TGA, XRD, FTIR, SAA, and CO2-TPD. The catalytic performance was compared with that of commercial calcium oxide under optimal reaction conditions, namely 50 °C temperature, 60 min reaction time, and 30 mg catalyst mass. The results showed that limestone-derived CaO produced a higher yield (44.6%) than commercial CaO (32.3%). The kinetics study showed that the reaction followed a two-order pseudo-kinetic model with a reaction rate constant value of 0.1450 L mmol-1 min-1. Overall, limestone-derived CaO proved to be an effective, inexpensive, and environmentally friendly alternative catalyst in the production of triglyceride-based biodiesel. Furthermore, the modification of CaO to enhance the catalytic activity needs to be explored further.
Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).